Oversimplification is very problematic
Piezoe.
I apologize for such a wordy response. You won't hurt my feelings if you skip much of it.
There are a couple things I could have better stated. One is that how good a particular gas is as a 'green house' gas depends on two things: 1. its absorptivity at the wavelengths of emr emitted by the Earth's surface; 2.
its concentration.
So I should
not have said, "Neither Water vapor nor CO2 is a good greenhouse gas." This is technically, if not incorrect, is at least misleading. CO2 is a weak green house gas and water is a somewhat more effective green house gas because of its concentration. Most of the gases in the atmosphere have no green house properties. A gases like methane and 'freons' have move IR active vibrational modes than either water or CO2 and are therefore potentially much better green house gases, but fortunately there is only trace amounts of either in the atmosphere, as your nice table shows.
I really like that kool video though it doesn't do much to explain the green house effect. It beautifully demonstrates that CO2 can absorb infra red, so the signal to his infrared camera goes away. (If he'd have used a camera sensitive to visible light only of course you wouldn't have seen anything because CO2 doesn't absorb in the visible.) Of course what's misleading here is that you get the impression CO2 is a strong absorber of IR, when actually it is a relatively weak absorber! Had he just let air into the tube you'd see no absorbance using his set-up, even though there would then be over 200 ppm CO2 in the tube. You could see the absorbance just fine of course with a regular IR gas spectrometer. But in this
case he's hooked his evacuated cylinder to a tank containing pure CO2 at about 2700-3200 psi. We are now on a planet far different than Earth. But anyway its a cool demonstration, even if a little misleading.
Here is a problem I see. Because this expression 'green house gas' has been so over used in the popular media many people just assume that the 'greenhouse mechanism' is the only mechanism that prevents our planet from plunging into very low temperatures at night like the moon for example. This is not true. The greenhouse mechanism is important. But Liquid water, which covers most of the Earth, is also very important in that regard. Water has a tremendously large specific heat that is greater than that of rock, sand, asphalt etc. This makes the oceans an almost unbelievably large heat sink for storage of thermal energy. Winds driven by differences in air density caused in turn by differences in thermal energy content (i.e., temperature) move the gases in our atmosphere over the Earths surface as well as from the Earth's surface to the upper atmosphere and back down. This convection facilitates transfer of thermal energy from the oceans to the land at night (the sea breeze) and vice versa during the day (the land breeze). Also we experience net IR radiation from the Oceans and land at night and net absorption of IR and visible and uv wavelengths during the day (the visible and uv reappear as longer wavelength IR when they are later emitted by these absorbing surfaces.) So it isn't just the atmosphere, and certainly not just CO2's green house effect that are responsible for moderating the temperature swings on our Earths surface, but a myriad of related phenomena as well , including many I haven't mentioned.
There is a guy here who continually posts that CO2 is a green house gas and therefore we should all be heating up if we continue to pump CO2 into the air. I cringe every time he does this because his over simplified view ignores the dependence of the green house effect on both absorptivities
and concentration and pays no attention to the relative role of CO2 in comparison with water and the myriad of mechanisms that are responsible for making our Earth habitable. He shows no understanding of the complexity of our climate mechanisms or the difficulties in modeling climate. He clearly does not understand that modeling is a tool for trying to understand specific mechanisms and how they might effect climate and temperature. So far there are no successful models that can accurately model our Earths climate system. It's chaotic and there is little possibility that the conventional approaches to modeling
will ever be successful in modeling a chaotic and very complex system. In this regard, I think former NASA-GISS physicist Ferenc Miskolczi's innovative approach* based on first principles and energy flow was a promising step forward. As with nearly every truly innovative approach, it may take years to be properly critiqued and vetted. But thank goodness someone is thinking in new directions because we are more or less at a dead end with the current approach. Sadly for sciences sake, GISS administrators tried to suppress publication of his work -- he resigned over it -- not because they could identify fatal flaws, but because it's conclusions did not support mainstream thinking. This is wrong, but scientists are also human and make mistakes for very human, as opposed to scientific, reasons. (*Note: Miskolczi was not attempting to model climate, rather he was addressing whether the assumptions in current models, eg., positive feedback, etc., could be supported from an energy flow perspective.)
You were wondering why we use use mole fraction 'X' to represent CO2 concentration. The reason we don't use a ppm value based on weight in this particular application is that if we are interested in the greenhouse effect, we are interested in the physical number of emr absorbers, not their weight. Thus mole fraction suits our purposes. Recall that a mole is just the name of a number, six times ten to the twenty-third, it has no dimensions and therefore no units. Just as we get % (percent is the same as parts per hundred or pph) by multiplying a dimensionless fraction based on any consistent measure, weight, volume, color, whatever, by 100, we can get ppm by multiplying mole fraction, a dimensionless number based on number of molecules, by one million. Therefore, if the ppm of CO2 is say 400ppm, based on mole fraction, then the mole fraction of CO2 is 400/1,000,000 or 0.0004.
You can interpret 400 ppm CO2 as 400 molecules of CO2 per every million molecules of atmosphere.
I'm not a climate denier, I'm a scientist whose is dismayed by the unprofessional conduct of some of my science colleagues, and one in particular, James Hansen. You can't decide scientific questions with media polls. The evidence is piling up that Hansen's original hypothesis, which proposed runaway catastrophic warming due to man induced rising CO2 is wrong. Other questions remain to be answered, and will be in time. We should not have pulled out of the climate accord, because regardless of Hansen's Hypothesis being dead wrong, there is great value in developing more environmentally friendly methods of energy production.
In my opinion Marshall Shepard is wrong regarding CO2 determining the Earths Temperature. It clearly does not. He is correct that temperature drives changes in atmospheric moisture; an important part of the negative feedback mechanism in response to both increasing and decreasing temperature. Without including positive feedback, the effects of changes in CO2 concentration we have seen in the past hundred years are far to feeble to be responsible for any significant mean change in global temperature, and the assumption of positive feedback which the probity of Shepard's often parroted explanation depends on, has been disproved. (Actually Shepard is parroting an explanation for CO2 driving temperature first advanced by GISS. It's wrong however. Solar irradience and geothermal energy release are vastly larger contributors to the Earths temperature than the very feeble effects of changes in CO2. And all of these contributors are countered by the Earths very effective negative feedback mechanism, featuring mainly water's role. The Earths temperature changes are cyclical rather than linear. The Earth under goes both warming periods and cooling periods but CO2, like water vapor, responds to these changes, rather then driving them. None of these considerations, however, rule out man's activities contributing to total atmospheric CO2 concentration.
By the way we always report the concentration non-condensing gases as the value in dry air, because otherwise the values would very due to relative humidity.