The full paper has been available for free if you click around you might find it.
I have probably linked to it here in the past. I read it.
1. conservation of mass is an amateur argument.
the earth absorbs co2, and there are articles showing it also off gases co2. We are far from a closed system.
2. The use of the differentiated time series is designed to show longer trends and eliminate the shorter term influence of seasonality.
Its well designed to pick up long term trends. Any seasoned trader knows that technique. The author of that critique obviously was throwing out buzzword without any comprehension.
3. CO2 has risen per data from mona loa.... Not sure how you could conclude natural co2 has not risen unless you disregard there are natural sinks and off gassing. I can show you charts showing the rise in co2 corresponds most closely with natural emissions and the human contribution does not.
here is more for your edification... we really don't have proof...
http://www.drroyspencer.com/2014/08/how-much-of-atmospheric-co2-increase-is-natural/7
As a first step, if we do simple correlations between the atmospheric CO2 variations with the other variables we find the highest correlation between temperature and CO2, and a little lower correlation with anthropogenic emissions:
Correlations with Yearly Atmospheric CO2 increases (1959-2012)
T_ocean : 0.70
T_land: 0.71
Fossil Fuels: 0.67
Ocean sink: 0.63
Land Use: -0.36
The fact that temperature has a higher correlation with yearly CO2 changes than does the anthropogenic source shows just how strongly the temperature variability affects atmospheric CO2 content.7
But correlating data with substantial trends in the data can be deceiving. Strictly speaking, all linear trends are perfectly correlated with each other, even those which have no causal relationship whatsoever between them.
So, we can
detrend all of the data, and see what information is contained in the departures from the linear trends. This reduces the correlations substantially, since the variability associated with the trends has been removed:
Correlations with Yearly Atmospheric CO2 variations (1959-2012, detrended)
T_ocean : 0.35
T_land: 0.34
Fossil Fuels: 0.13
Ocean sink: 0.01
Land Use: 0.00
We see that the correlation between atmospheric CO2 and temperature remains the strongest, but the fossil fuel signal is very small, possibly because the detrended variations in anthropogenic emissions are quite small, and so subject to greater errors.
more at link...