I am not really all that familiar with USO... Do options on it really trade frequently enough for you to be able to observe fluctuations that you show on the chart?
http://www.nasdaq.com/symbol/uso/option-chain
It's fairly liquid and widely held (high OIs for near the money options).
Also the calculation is using midpoint of Bid/Ask, and as long as bid/ask are comparatively OK (otherwise arbs will step in), the IV should not be way too off.