I apologize for bumping an old thread, i.e. if it's a faux pas around here, but anyhow to answer your question simply put yes can you trade "volatility".
Strictly speaking, if you're looking to trade realized volatility you would probably want to look into trading a variance swap. However, the problem with that is most retail investors, which I'm assuming you are, do not have access to such instruments. Although, you can do a static replication of a variance swap with vanilla options (I suspect the cost may be high though).
In the retail scheme, what seems a bit more accessible would be actually trading the difference between realized and implied volatility. You could probably do this by just gamma scalping (i.e. dynamically delta hedging the underlyer), the gamma moves would offset your theta losses. Depending on what your transaction costs are and the amount of haircut you have, this could be highly feasible.
Hope that helped!