The gimmick of this riddle is the fact that the door that is opened is not randomly chosen. It will never reveal the car, it is guaranteed to reveal one of the two goats.
This tells you nothing you didn't already know, except for which of the three doors does not contain the car.
Let's say you chose door #3 to begin with.
The original odds of the car being behind:
either door #1 or door #2 is 66.6%
either door #1 or door #3 is 66.6%.
either door #2 or door #3 is 66.6%.
While it is true that door #1 and door #2 together constitute a group which has 66.6% probability of containing the car in the first place, the fact is that #1+#3 and #2+#3 also constitute groupings with 66.6% probability of containing the car. Thus your original selection necessarily belongs to two out of three of the 66.6% probability groups. The odds are 2 out of 3 that your door will belong to a pairing of doors containing the car. The odds of the car being behind the door you selected is exactly equal to the odds of it being behind any individual door from any pair of doors.
Revealing the goat from one of the two unselected doors alters the probability of the car being behind all three pairings of doors.
Let's say the inevitable goat is shown behind door #1.
The odds of the car being behind:
either door #1 or door #2 is now 50%
either door #1 or door #3 is now 50%
either door #2 or door #3 is now 100%
The revealed goat alters the relative probabilities of the three pairings of doors, but not of the remaining individual unopened doors. They are still equal. The odds of your door now containing the car is still 50%, not 33.3%, even though you know the door which revealed the goat was not chosen randomly in 2/3 of the cases. This is because although door #2 belongs to the group #1+#2 which originally had the 66.6% probability of containing the car, door #3 also belongs to two pairings that originally had a 66.6% probability of containing the car. After door #1 has been shown to contain a goat, door #2 and door #3 both belong to the only pair guaranteed to contain the car. Since they both belong to the same winning group, their odds of containing the car are exactly equal.
Should I switch my original selection expecting to double my odds of winning? Naaaaaaaaaaaaaaah!
This tells you nothing you didn't already know, except for which of the three doors does not contain the car.
Let's say you chose door #3 to begin with.
The original odds of the car being behind:
either door #1 or door #2 is 66.6%
either door #1 or door #3 is 66.6%.
either door #2 or door #3 is 66.6%.
While it is true that door #1 and door #2 together constitute a group which has 66.6% probability of containing the car in the first place, the fact is that #1+#3 and #2+#3 also constitute groupings with 66.6% probability of containing the car. Thus your original selection necessarily belongs to two out of three of the 66.6% probability groups. The odds are 2 out of 3 that your door will belong to a pairing of doors containing the car. The odds of the car being behind the door you selected is exactly equal to the odds of it being behind any individual door from any pair of doors.
Revealing the goat from one of the two unselected doors alters the probability of the car being behind all three pairings of doors.
Let's say the inevitable goat is shown behind door #1.
The odds of the car being behind:
either door #1 or door #2 is now 50%
either door #1 or door #3 is now 50%
either door #2 or door #3 is now 100%
The revealed goat alters the relative probabilities of the three pairings of doors, but not of the remaining individual unopened doors. They are still equal. The odds of your door now containing the car is still 50%, not 33.3%, even though you know the door which revealed the goat was not chosen randomly in 2/3 of the cases. This is because although door #2 belongs to the group #1+#2 which originally had the 66.6% probability of containing the car, door #3 also belongs to two pairings that originally had a 66.6% probability of containing the car. After door #1 has been shown to contain a goat, door #2 and door #3 both belong to the only pair guaranteed to contain the car. Since they both belong to the same winning group, their odds of containing the car are exactly equal.
Should I switch my original selection expecting to double my odds of winning? Naaaaaaaaaaaaaaah!

The illusion of logic that makes this riddle is the assumption that "after your first choice there are two groups", one with 33% odds and one with 66% odds. The fact is, that after your first choice there are three groups, all with equal probabilities. Comparing probabilities of groups vs. individuals is comparing apples to oranges. It creates a numerical illusion, but not a statistical fact.You should switch from your first choice to the remaining closed door, and by doing so you increase your probability of choosing the auto from 33% to 67%. Initially this may seem to be counter-intuitive, because there are two remaining doors that ORIGINALLY had the same probability of hiding the car (33% for each of the three).
Consider however that after your first choice there are two groups, your choice which has 33% likelyhood, and the group of the other two which have combined 67% likelyhood. Since there is always at least one goat in the second group of two doors, the game show host does not change the relative likelyhood by showing you one goat (no new info about the two groups). What he does allow you to do is capture the entire 67% likelyhood by picking the remaining door of that second group.