If you are really interested in learning how options behave from a fundamental point of view... thus Delta, gamma, theta, vega...
Than I would recommend to start with:
Natenburg (already mentioned) followed by the book:
"Options: Perception and deception" from C.M. Cottle.
While reading the books I would recommend to use a good option calculator. (there are many free ones online) eg. straddleplanner.com.
I (still) recommend covered call writing for BEGINNERS as a method for quickly understanding how options work and how to trade them.
Then I encourage them to move on to more conservative strategies, with limited risk.
In my opinion, invesors who already invest in stock are far better served by writing covered calls than they would be by gambling by buying options. And buying options is the typical method taught my most books for option rookies.